Polymer-based material coating with tuneable optical properties
Researchers have developed a coating that can be used to create tuneable optical components, which could one day be used in optical signal processing, potentially enabling faster and more energy-efficient AI
Researchers from the University of Jena have developed a material coating whose light refraction properties can be precisely switched between different states. The scientists combined polymers that react to light with so-called meta-surfaces, and this innovation has led to the creation of new optical components with the potential to be used in signal processing. The interdisciplinary team, led by Felix Schacher, Sarah Walden, Purushottam Poudel, and Isabelle Staude, have now published their findings in the journal ACS Nano.
“Both meta-surfaces and light-switchable polymers have been known in principle for decades,” explains Sarah Walden from the Institute of Solid State Physics, who now leads a research group in Australia, “but we are the first to combine both in this form to develop new components for optical applications.”
Meta-surfaces are nanostructured thin layers whose characteristic structural sizes are smaller than the wavelength of light. This allows the properties of light and its propagation to be specifically influenced, enabling a variety of optical functions that would otherwise be performed by lenses, polarisers, or gratings. On the other hand, switchable polymers are plastics whose properties – such as the light refraction index – can change between different states.
“The polymers we used contain dye molecules,” Felix Schacher from the Institute of Organic Chemistry and Macromolecular Chemistry continues. “This means that they absorb light of a certain wavelength and, in doing so, change their structure – and thus their properties, such as the refractive index of light in this case.”
To switch the dye back to its previous structure with the corresponding property, light of a different wavelength is required. “What's special about our system,” explains physicist Isabelle Staude, “is that the changes in refractive index affect the optical properties of the meta-surface when it is coated with such a polymer.”
The researchers say the changes achieved were surprisingly significant, even compared to previously known similar systems. “Because the polymers show different absorption depending on the dye, various effects can be very well separated from one another or combined,” Staude summarises.
Besides this promising result, the team also reported a surprising discovery: “In our work, we used two different dyes separately, each applied to a meta-surface. This confirmed the effect,” Schacher says. “However, when mixing both switchable polymers, additional effects occur. We suspect that the two different dye molecules interact with each other, but we cannot say for certain at this point.” Further investigations are needed to clarify this interesting behaviour.
Although the primary focus with these switchable surfaces was to demonstrate the basic principle, the research group envision several potential applications: “Since these surfaces can switch between different property states with light, sensor technology is a natural application area.”
It is also conceivable that such switchable surfaces could be used for optical data processing. “Of course, it would delight our team if these components could be used for optical neural networks, for example, which could then process image information in the same way that electronic artificial intelligence can now,” says Schacher. “However, because this type of data processing is based on light rather than electronics, it is significantly more energy-efficient and faster than traditional computer-based AI.”
Image credit: Jens Meyer (University of Jena)
